English
norskBlar i forfatter "Norheim, Hans-Kristian"
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Ligand noninnocence in FeNO corroles: insights from β-octabromocorrole complexes
(Journal article; Tidsskriftartikkel; Peer reviewed, 2015-11-30)The first FeNO octabromocorroles have been synthesized including four β-octabromo-meso-tris(p-X-phenyl)corrole derivatives Fe[Br8TpXPC](NO) (X = CF3, H, CH3, OCH3) and the β-octabromo-meso-tris(pentafluorophenyl)corrole complex, Fe[Br8TPFPC](NO). The last complex, which proved amenable to single-crystal X-ray structure determination, exhibits the geometry parameters: Fe–N(O) 1.643(8) Å, N–O 1.158(9) ... -
One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction.
(Journal article; Tidsskriftartikkel; Peer reviewed, 2017-02-14)A one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octabromo-meso-tris (2,6-dibromo-3,5-dimethoxyphenyl) corrole, a new bis-pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to MnIII and AuIII. A single-crystal X-ray structure was ... -
One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction
(Journal article; Tidsskriftartikkel; Peer reviewed, 2017-02-14)A one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper beta-octabromo-meso-tris(2,6-dibromo-3,5-dimethoxyphenyl)corrole, a new bis-pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to Mn<sup>III</sup> and Au<sup>III</sup>.A single-crystal ...
